Optically active polymers bearing side-chain photochromic moieties: synthesis and chiroptical properties of methacrylic homopolymers with pendanttrans-azobenzene chromophores bound throughL-leucine,L-valine andL-proline amino acid spacers

2000 ◽  
Vol 201 (13) ◽  
pp. 1540-1551 ◽  
Author(s):  
Carlo Carlini ◽  
Adriano Fissi ◽  
Anna Maria Raspolli Galletti ◽  
Glauco Sbrana
Keyword(s):  
Amino Acid ◽  
Optically Active ◽  
Side Chain ◽  
Optically Active Polymers ◽  
Chiroptical Properties ◽  
Proline Amino Acid

Optically active polymers containing side-chain trans-stilbene chromophores directly bound to the backbone: photochemistry and photophysics of copolymers of (-)-menthyl acrylate with trans-4-vinylstilbene

1985 ◽  
Vol 18 (4) ◽  
pp. 729-734 ◽  
Author(s):  
Angelina Altomare ◽  
Carlo Carlini ◽  
Francesco Ciardelli ◽  
Mario Panattoni ◽  
Roberto Solaro ◽  
...  
Keyword(s):  
Optically Active ◽  
Side Chain ◽  
Optically Active Polymers ◽  
Trans Stilbene

Methacrylic polymers bearing side-chain permanent dipole azobenzene chromophores spaced from the main chain by chiral moieties, 3 a Synthesis and chiroptical properties of the homopolymer of (R)-3-methacryloyloxy-1-(4’-nitro-4-azobenzene)- pyrrolidine and of copolymers with the enantiomeric monomer (S)-3-methacryloyloxy-1-(4’-nitro-4-azobenzene)- pyrrolidine

e-Polymers ◽  
2003 ◽  
Vol 3 (1) ◽  
Author(s):  
Luigi Angiolini ◽  
Loris Giorgini ◽  
Elisabetta Salatelli
Keyword(s):  
Radical Polymerization ◽  
Optical Activity ◽  
Main Chain ◽  
Optically Active ◽  
Side Chain ◽  
Chiroptical Properties

Abstract The optically active photochromic homopolymer deriving from radical polymerization of the monomer (R)-3-methacryloyloxy-1-(4’-nitro-4-azobenzene)- pyrrolidine, containing a chiral group of one prevailing configuration interposed between the methacrylic moiety and the photochromic azoaromatic chromophore, has been synthesized and characterized. Copolymers with the enantiomeric monomer (S)-3-methacryloyloxy-1-(4’-nitro-4-azobenzene)pyrrolidine have also been prepared in order to evaluate the effect on the overall optical activity of side chain chiral groups of opposite configuration in various ratios. The spectroscopic and chiroptical properties in solution of the polymeric derivatives have been assessed.

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